Tis might resurrect an old issue but i encountered this on my machine today.
i am using Daemon tools pro version 4.35.0306.0088
and is trying to mount a mdf file directly since i am missing the .mds file.
trying tips in another thread "Unable to mount image. File not accessible" did'nt work.
After some testing i came up with a solution by using the image editor and saving the image which generated a .mds file using that mounting the image worked just fine.
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