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The mount to physical device feature don't work with non-ATAPI devices.
Please specify what Windows OS? Please also specify the SPTD version that installed.
Can you also tell what controller is used to your CD-ROM? You see it please go to Device manager - DVD\CD-ROM drivers. Select your optical drive and go to View - Devices by connection where you can see the connection type (as example look at screenshots):
Here is how the situation looks like on my PC:
I still cannot understand what is wrong and why I get this freaking message "No devices were found"... Maybe the CD-ROM should be connected to ATA Channel 0 not 1. I don't know...
Please, help me fix this issue !